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- W1970092164 abstract "The FFC Cambridge process is a direct electrodeoxidation process used to reduce metal oxides to their constituent metals in a molten salt bath. was used as a precursor (the first stable oxide to form upon blending and sintering NiO and powders) and was successfully reduced using the FFC Cambridge process at and a constant cell voltage of to produce a NiTi alloy. This work builds on the literature work [ Chinese Science Bulletin , 51 , 2535 (2006) ] through: (i) a predominance diagram calculated to show the regions of phase stability throughout the usable potential window of the salt; (ii) the investigation of a wide range of reduction times for a fixed cell voltage, elucidating several additional stable phases, to yield a complete and detailed reduction pathway. The reduction pathway for was identified through the analysis of a series of partial reductions, with fully reduced NiTi formed after a period of . The first stage of the reaction involved the rapid formation of Ni and . The reduction then proceeded via the formation of the intermediate compounds and . All the and Ni were consumed after a period of , while the intermediate compounds remained until the reaction was near completion. The experimental results related well to the thermodynamic predictions of the predominance diagram. A small variation in stoichiometry of the produced NiTi observed from the edge to the core of the samples was attributed to redeposition of Ti on the sample surface from the salt and a slightly Ti-rich precursor material." @default.
- W1970092164 created "2016-06-24" @default.
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- W1970092164 date "2008-01-01" @default.
- W1970092164 modified "2023-09-26" @default.
- W1970092164 title "Production of NiTi via the FFC Cambridge Process" @default.
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- W1970092164 doi "https://doi.org/10.1149/1.2987739" @default.
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