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- W19701092 abstract "“Living” polypropylene of uniform chain length was prepared by low-temperature polymerization of propene with some soluble vanadium-based catalysts. The chain end structure of living polypropylene was studied by 1H NMR analysis of iodine-bonded polypropylene. 1H NMR analysis revealed that the majority of active centers exist as a secondary vanadium-carbon bond during the chain propagation of living polypropylene. The mechanism of the living coordination polymerization is discussed based on kinetic and stereochemical data." @default.
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- W19701092 date "1986-01-01" @default.
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- W19701092 title "Structure and Reactivity of “Living” Polypropylene" @default.
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- W19701092 doi "https://doi.org/10.1016/s0167-2991(09)60331-1" @default.
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