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- W1970109493 abstract "The rotational spectra of azulene in the ground and six vibrationally excited states have been measured in the frequency range from 7.4 to 12.5 GHz. Rotational constants and centrifugal distortion constants have been determined for all measured states from R- and Q-branch transitions. The results for the ground state are: A = 2841.9531 ± 0.0029 MHz, B = 1254.8449 ± 0.0013 MHz, C = 870.7148 ± 0.0010 MHz, τaaaa = −0.417 ± 0.367 kHz, τbbbb = −0.281 ± 0.079 kHz, τaabb = −0.553 ± 0.440 kHz, and τabab = 0.029 ± 0.175 kHz. A method is described which was followed for the measurement of relative intensities of absorption lines in vibrationally excited states. Accurate results have been obtained for three states belonging to different normal vibrations. The corresponding vibrational frequencies of these lowest fundamentals of azulene were found to be 272.7 ± 5.0 cm−1 (B2), 188.0 ± 2.4 cm−1 (A2), and 180.3 ± 1.9 cm−1 (B2). Spin-statistical weights and changes of the inertia defect have been used to assign the symmetry species." @default.
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- W1970109493 date "1972-07-01" @default.
- W1970109493 modified "2023-10-03" @default.
- W1970109493 title "Microwave spectra of vibrationally excited states of azulene" @default.
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- W1970109493 doi "https://doi.org/10.1016/0022-2852(72)90159-2" @default.
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