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- W1970119472 abstract "The reaction mechanism of cell Li/PbS has been studied with coulombic titration, cyclic voltammetry and X-ray diffraction methods. It was found that in the first stage of discharge (0< y ≤1.5), the intercalation of lithium into lead sulfide took place. The X-ray diffraction patterns showed that the main crystalline structure of PbS remained unchanged after lithiation, and the lithium intercalated probably locates in the center of the cubic-interspace of the crystal. The intercalation free energy of Li into PbS forming LiPbS was found to be −300.48 KJ·mol−1 (at 25°C). The chemical diffusion coefficient of lithium in LiyPbS (0<y≤1) was determined by electrochemical method to be about 10−11 cm2S-1." @default.
- W1970119472 created "2016-06-24" @default.
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- W1970119472 date "1987-11-01" @default.
- W1970119472 modified "2023-09-24" @default.
- W1970119472 title "Electrochemical intercalation reaction of lithium into sulfides of nonlayer structure: I. Lithium intercalation in lead sulfide" @default.
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- W1970119472 doi "https://doi.org/10.1002/cjoc.19870050402" @default.
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