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- W1970120997 abstract "Both the molar enthalpies of formation and the absolute entropies of eight transition metal oxides are found to correlate very strongly with their formula unit volumes at room temperature. The metals are Ti, V, Cr, Nb, Mo, Ce, Pr, and Tb. In particular, the thermodynamic values of additive entities (such as TiO2 in TinO2n−1) in Magnéli phases (that is, recombination phases based on rebuilding after shear) are very close to those of the entity as a pure compound. Thus, reliable values of these thermodynamic properties can readily be predicted for unmeasured or even unsynthesized examples, and literature values can be checked. These assertions are checked against published results for which incomplete data is available. The contributions of the disordered regions which form between the added entities is tentatively estimated." @default.
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- W1970120997 date "2009-10-08" @default.
- W1970120997 modified "2023-09-23" @default.
- W1970120997 title "Systematic Thermodynamics of Magnéli-Phase and Other Transition Metal Oxides" @default.
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- W1970120997 doi "https://doi.org/10.1021/ic901395z" @default.
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