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- W1970139274 abstract "This paper illustrates a novel use of factor analysis to characterize models for infinite dilution activity coefficients. Different forms of a modified cohesive energy density (MOSCED) equation were used to create synthetic data matrices to be analyzed by factor analysis. The abstract factors from these matrices were used to target test the different model parameters. By using the synthetic data, the factors contributing to the different forms of the MOSCED equation that were most susceptible to noise were identified. Factor analysis and target testing were then used to characterize a database of experimental infinite dilution activity coefficients for 29 solvents and 31 solutes. The factor analysis results for one form of the MOSCED equation were used to evaluate different physicochemical scales for dispersion, dipolarity and hydrogen bonding interactions." @default.
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- W1970139274 date "1993-05-01" @default.
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- W1970139274 title "Developing models for infinite dilution activity coefficients using factor analysis methods" @default.
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- W1970139274 doi "https://doi.org/10.1016/0003-2670(93)80436-o" @default.
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