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• W1970147767 abstract "Thermal reaction of alkynyl propargyl sulfoxides 1 afforded novel highly reactive (α-ketovinyl)thioketenes 3. Trapping experiments using a primary or secondary amine, formation of furanophane 4, through head-to-tail type dimerization, as well as direct observation using 1H NMR elucidated the generation pathway of 3 through sequential [2,3]/[3,3] sigmatropic rearrangement." @default.
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• W1970147767 date "2007-06-01" @default.
• W1970147767 modified "2023-10-18" @default.
• W1970147767 title "Novel generation of (α-ketovinyl)thioketenes as intermediates through tandem [2,3]/[3,3] sigmatropic rearrangement of alkynyl propargyl sulfoxides" @default.
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• W1970147767 doi "https://doi.org/10.1016/j.tetlet.2007.04.055" @default.
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