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- W1970192811 abstract "Trimetallic dithio-tetraseleno-cyanate, Pb[(EtOH)2NiHg(SeCN)4(SCN)2] and diseleno-tetrathio-cyanate, Pb[(EtOH)2NiHg(SCN)4(SeCN)2] have been synthesized and characterized. These compounds have been used as Lewis-acids and their complexes with PPh3, dmso, py, bipy and phen have also been synthesized and studied. IR Spectral, electronic spectral, magnetic moment and molar conductance studies indicate that lead is in the form of a cation Pb2+ or PbL44+ with the anions [(L)2NiHg(SeCN)4(SCN)2]2− or [(L)2NiHg(SCN)4(SeCN)2]2−. In the anion nickel and mercury are linked through selenocyanate bridges and the remaining thiocyanate or selenocyanate groups are attached through either of their terminal ends. Matching on the basis of HSAB principles has also been used to support the structures." @default.
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- W1970192811 date "1981-01-01" @default.
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- W1970192811 title "Synthesis and structure of Pb[(EtOH)2NiHg(SeCN)4(SCN)2] and its complexes" @default.
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- W1970192811 doi "https://doi.org/10.1016/0022-1902(81)80439-3" @default.
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