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• W1970220160 abstract "Abstract A comprehensive mathematical model for atom transfer radical copolymerization in a batch reactor is presented using the concept of pseudo‐kinetic rate constants and the method of moments. The model describes molecular weight, monomer conversion, polydispersity index, and copolymer composition as a function of polymerization time. Model predictions were compared with experimental data for styrene and butyl acrylate copolymerization and excellent agreement was obtained. We have also tested the model with styrene‐acrylonitrile copolymerization data obtained in our laboratory. Finally, we used the model to study the effect of comonomer reactivity ratio, feed composition, activation and deactivation rate constants on the copolymer composition. magnified image" @default.
• W1970220160 created "2016-06-24" @default.
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• W1970220160 creator A5005700484 @default.
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• W1970220160 date "2007-07-05" @default.
• W1970220160 modified "2023-10-10" @default.
• W1970220160 title "Mathematical Modeling of Atom-Transfer Radical Copolymerization" @default.
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• W1970220160 doi "https://doi.org/10.1002/mren.200700008" @default.
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