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• W1970237158 endingPage "102" @default.
• W1970237158 startingPage "95" @default.
• W1970237158 abstract "The content of several works effected on the electrochemical polymerization of several pyrroles and thiophenes is given and exemplified. It is shown that the polymerization of pyrroles proceeds via a cation-radical coupling. In the case of thiophenes, the electrochemistry of end-capped oligomers giving stable cation radicals has been first examined. The existence of associated forms of the cation radicals, the π-dimers, has been demonstrated, and the formation parameters of these π-dimers have been determined using only the electrochemical analysis of the reversible voltammograms in solution. On the other hand, the σ-polymerization of some polymerizable thiophene oligomers (quinquethiophenes and trimethylsilylterthiophenes) has been examined, and it is also shown that the preferred process in acetonitrile or dichloromethane is a cation-radical/cation-radical coupling." @default.
• W1970237158 created "2016-06-24" @default.
• W1970237158 creator A5025296422 @default.
• W1970237158 creator A5031610103 @default.
• W1970237158 date "1995-12-01" @default.
• W1970237158 modified "2023-09-30" @default.
• W1970237158 title "Fast electrochemical studies of the polymerization mechanisms of pyrroles and thiophenes. Identification of the first steps. Existence of π-dimers in solution" @default.
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• W1970237158 doi "https://doi.org/10.1016/0379-6779(95)03396-2" @default.
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