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- W1970238214 abstract "Hexafluoroacetone has been photolyzed with HCl and with mixtures of HCl+Cl2, HCl+Br2, Br2+Cl2, and Cl2+HBr. Absolute Arrhenius parameters have been obtained for the reaction, CF3+HCl→CF3H+Cl (4) using the combination of CF3 radicals as a reference reaction. The values of A4 and E4 have been combined with the results obtained from competitive experiments on the above pairs of reactants and from previous work to give other Arrhenius parameters as follows: CF3+HCl→CF3H+Cl k= 1.7 × 1011 exp (–5100/RT) CF3+HBr→CF3H+Br k= 6.0 × 1011 exp (–2900/RT) CF3+Cl2→CF3Cl+Cl k= 7.7 × 1012 exp (–3600/RT) CF3+Br2→CF3Br+Br k= 2.3 × 1012 exp (–700/RT) CF3+I2→CF3I+I k= 2.6 × 1012 exp (0/RT) units; cm3mole–1sec–1" @default.
- W1970238214 created "2016-06-24" @default.
- W1970238214 creator A5018762602 @default.
- W1970238214 creator A5091658088 @default.
- W1970238214 date "1966-01-01" @default.
- W1970238214 modified "2023-09-30" @default.
- W1970238214 title "Reactions of trifluoromethyl radicals with bromine, chlorine and hydrogen chloride" @default.
- W1970238214 doi "https://doi.org/10.1039/tf9666201662" @default.
- W1970238214 hasPublicationYear "1966" @default.
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