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- W1970245280 abstract "Reaction of p-phenylhexahomocalix[3]arene (I-H) with bromomethyl acetate and potassium carbonate in acetone leads to the title triester derivative, (I-CH 2 CO 2 Et) {triethyl 7,15,23-triphenyl-3,11,19-trioxatetracyclo[19.3.1.1 5,9 .1 13,17 ]heptacosa-1(25),5,7,9(27),13,15, 17(26),21,23-nonaene-25,26,27-triyltris(oxyacetate), C 54 H 54 O 12 }, in a partial-cone conformation, which crystallizes with two molecules in the asymmetric unit. In this conformation, (I-CH 2 CO 2 Et) is adapted for selective complexation of the K + cation. We describe in this paper the synthesis and conformational behaviour of (I-CH 2 CO 2 Et) as determined by 1 H NMR spectroscopy and X-ray diffractometry" @default.
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- W1970245280 date "1995-01-15" @default.
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- W1970245280 title "7,15,23-Triphenyl-25,26,27-triethylester-2,3,10,11,18,19-hexahomo-3,9,11-trioxacalix[3]arene in a Partial-Cone Conformation" @default.
- W1970245280 doi "https://doi.org/10.1107/s0108270194008036" @default.
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