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- W1970291286 abstract "The title subject has been studied by quasi-stationary (20 h stabilization) and transient polarization measurements and dc capacitance determinations over potentials from −0.3 to 3 V (sce) in sulphate, chloride and acetate solutions of pH 0–7 at 25°C. The quasi-stationary data show an essentially potential and anion independent anodic passive current which is rather low and partly pH dependent, and a partial anodic current of solution oxidation (electron transfer) appearing at high potentials. The transients accord with the Cabrera—Mott equation and suggest that the ion transfer at the metal/oxide interface is mostly by Ti(IV) ions. The capacitance data largely obey expectations from an “insulator” model and combine with previous ellipsometric data to reveal the main charge and potential distribution at the passive titanium electrode. This electrode seems always to carry a net negative charge, which may explain its inertness to solution anions." @default.
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- W1970291286 date "1986-09-01" @default.
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- W1970291286 title "Passive behaviour of titanium" @default.
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- W1970291286 doi "https://doi.org/10.1016/0013-4686(86)80126-8" @default.
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