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- W1970292289 abstract "The electrochemical oxidation of 5-methyl-5,6,7,8-tetrahydropterin (5-MTHP) in aqueous solution has been studied. At, for example, pH 4.7 the primary oxidation reaction responsible for the first voltammetric oxidation peak appears to proceed by two pathways. The first of these is a 2e−2H+ process leading to a cationic intermediate that loses a methyl carbonium ion yielding the same quinonoid-dihydropterin formed on 2e−2H+ electrooxidation of 5,6,7,8-tetrahydropterin. This quinonoid-dihydropterin then undergoes rearrangement to 7,8-dihydropterin that in its covalently hydrated form is further oxidized yielding pterin and 7,8-dihydroxanthopterin. The second route does not cause demethylation of 5-MTHP and yields 5-methyl-7,8-dihydroxanthopterin." @default.
- W1970292289 created "2016-06-24" @default.
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- W1970292289 date "1984-01-01" @default.
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- W1970292289 title "Electrochemical oxidation of 5-methyl-5,6,7,8-tetrahydropterin" @default.
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- W1970292289 doi "https://doi.org/10.1016/s0022-0728(84)80121-7" @default.
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