FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1970321021> ?p ?o ?g. }

• W1970321021 endingPage "286" @default.
• W1970321021 startingPage "275" @default.
• W1970321021 abstract "The synthesis and molecular structures of the (Tp*)Mo(NO)(SS) family of compounds (where (Tp*) is hydrotris(3,5-dimethyl-1-pyrazolyl)borate; (SS) is an ene-1,2-dithiolate) are reported. The compounds; (Tp*)Mo(NO)(bdt) (1), (Tp*)Mo(NO)(tdt) (2), and (Tp*)Mo(NO)(bdtCl2) (3) (bdt, 1,2-benzenedithiolate; tdt, 3,4-toluenedithiolate; bdtCl2, 3,6-dichlorobenzenedithiolate), are the first such structurally characterized {MoNO}4 compounds that contain a [(Tp*)Mo(NO)]2+ fragment ligated to an ene-1,2-dithiolate. The compounds crystallize in the space groups P21/c (1) (a=11.115(2) Å, b=13.667(3) Å, c=16.410(3) Å; β=98.36(3)°, Volume=2466.4(8) Å3, Z=4); P21/n (2) (a=15.579(3) Å, b=9.942(2) Å, c=16.527(3) Å; β=95.79(3)°, Volume=2546.7(9) Å3, Z=4); and Pnma (3) (a=17.9879(9) Å, b=13.2277(7) Å, c=11.2505(6) Å; Volume=2676.9(2) Å3, Z=4). The molecular structures show that the inner coordination sphere remains invariant within this family. A remarkable feature is the fold angle (θ) between the MoS2 plane and S2C2 plane of the ene-1, 2-dithiolate chelate ring. The fold angles (θ) of 42.1° in 1, 41.1° in 2 and 44.4° in 3 are substantially larger than in analogous compounds with a terminal oxo group. Additional insight into the chemistry and properties of complexes 1–3 has been obtained by cyclic voltammetry, IR, NMR, electronic absorption and He I photoelectron (PES) spectroscopies." @default.
• W1970321021 created "2016-06-24" @default.
• W1970321021 creator A5018957391 @default.
• W1970321021 creator A5044119337 @default.
• W1970321021 creator A5045726141 @default.
• W1970321021 creator A5060073386 @default.
• W1970321021 creator A5071089465 @default.
• W1970321021 creator A5075543657 @default.
• W1970321021 creator A5079361519 @default.
• W1970321021 date "2002-09-01" @default.
• W1970321021 modified "2023-09-25" @default.
• W1970321021 title "Six-coordinate molybdenum nitrosyls with a single ene-1,2-dithiolate ligand" @default.
• W1970321021 cites W1580450890 @default.
• W1970321021 cites W1963764375 @default.
• W1970321021 cites W1968461848 @default.
• W1970321021 cites W1969626263 @default.
• W1970321021 cites W1970951785 @default.
• W1970321021 cites W1973660405 @default.
• W1970321021 cites W1982424801 @default.
• W1970321021 cites W1983970644 @default.
• W1970321021 cites W1988841674 @default.
• W1970321021 cites W1991229774 @default.
• W1970321021 cites W1993972320 @default.
• W1970321021 cites W1994412962 @default.
• W1970321021 cites W1994595353 @default.
• W1970321021 cites W1995901106 @default.
• W1970321021 cites W1997167908 @default.
• W1970321021 cites W2003416747 @default.
• W1970321021 cites W2005639025 @default.
• W1970321021 cites W2011413203 @default.
• W1970321021 cites W2018053239 @default.
• W1970321021 cites W2022073730 @default.
• W1970321021 cites W2024681640 @default.
• W1970321021 cites W2025321164 @default.
• W1970321021 cites W2026961787 @default.
• W1970321021 cites W2028348431 @default.
• W1970321021 cites W2031592258 @default.
• W1970321021 cites W2034603739 @default.
• W1970321021 cites W2035160040 @default.
• W1970321021 cites W2039456463 @default.
• W1970321021 cites W2044269503 @default.
• W1970321021 cites W2046081922 @default.
• W1970321021 cites W2055111778 @default.
• W1970321021 cites W2058088283 @default.
• W1970321021 cites W2061088755 @default.
• W1970321021 cites W2061487555 @default.
• W1970321021 cites W2063477756 @default.
• W1970321021 cites W2069856258 @default.
• W1970321021 cites W2071526219 @default.
• W1970321021 cites W2071929415 @default.
• W1970321021 cites W2078362548 @default.
• W1970321021 cites W2087753213 @default.
• W1970321021 cites W2088786515 @default.
• W1970321021 cites W2089072541 @default.
• W1970321021 cites W2089452279 @default.
• W1970321021 cites W2091776447 @default.
• W1970321021 cites W2151512656 @default.
• W1970321021 cites W2166771636 @default.
• W1970321021 cites W2950440797 @default.
• W1970321021 cites W3005055650 @default.
• W1970321021 cites W4235155537 @default.
• W1970321021 cites W4235247238 @default.
• W1970321021 cites W4245399940 @default.
• W1970321021 doi "https://doi.org/10.1016/s0020-1693(02)01127-1" @default.
• W1970321021 hasPublicationYear "2002" @default.
• W1970321021 type Work @default.
• W1970321021 sameAs 1970321021 @default.
• W1970321021 citedByCount "25" @default.
• W1970321021 countsByYear W19703210212012 @default.
• W1970321021 countsByYear W19703210212013 @default.
• W1970321021 countsByYear W19703210212014 @default.
• W1970321021 countsByYear W19703210212016 @default.
• W1970321021 countsByYear W19703210212019 @default.
• W1970321021 crossrefType "journal-article" @default.
• W1970321021 hasAuthorship W1970321021A5018957391 @default.
• W1970321021 hasAuthorship W1970321021A5044119337 @default.
• W1970321021 hasAuthorship W1970321021A5045726141 @default.
• W1970321021 hasAuthorship W1970321021A5060073386 @default.
• W1970321021 hasAuthorship W1970321021A5071089465 @default.
• W1970321021 hasAuthorship W1970321021A5075543657 @default.
• W1970321021 hasAuthorship W1970321021A5079361519 @default.
• W1970321021 hasConcept C11111787 @default.
• W1970321021 hasConcept C115624301 @default.
• W1970321021 hasConcept C116569031 @default.
• W1970321021 hasConcept C170493617 @default.
• W1970321021 hasConcept C178790620 @default.
• W1970321021 hasConcept C179104552 @default.
• W1970321021 hasConcept C185592680 @default.
• W1970321021 hasConcept C27777614 @default.
• W1970321021 hasConcept C501308230 @default.
• W1970321021 hasConcept C549387045 @default.
• W1970321021 hasConcept C55493867 @default.
• W1970321021 hasConcept C71240020 @default.
• W1970321021 hasConcept C8010536 @default.
• W1970321021 hasConceptScore W1970321021C11111787 @default.
• W1970321021 hasConceptScore W1970321021C115624301 @default.
• W1970321021 hasConceptScore W1970321021C116569031 @default.
• W1970321021 hasConceptScore W1970321021C170493617 @default.

• next