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• W1970352016 abstract "Abstract The Baker's Yeast (BY) reduction of ( Z )-2-chloromethyl-3-arylacrylaldehydes was found to afford ( R )-2-methyl-3-aryl-propanols showing high enantiomeric excess values. Deuterium incorporation experiments were performed, in order to investigate the mechanism of the bioreduction: the formation of the corresponding substituted 2-benzylacrylaldehydes, as intermediates to be effectively reduced by Baker's Yeast, was suggested. These intermediates were synthesized and submitted to BY reduction to afford the corresponding saturated ( R )-alcohols, thus confirming the conclusions drawn from labelling experiments. The enantioselectivity of their bioreduction was found to be opposite with respect to that observed for the corresponding regioisomeric 2-methylcinnamaldehydes. The preparation of the two enantiomers of 2-methyl-3-aryl-propanols by fermentation of two regioisomers represents an interesting example of substrate-controlled enantioselective reaction." @default.
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• W1970352016 date "2012-12-01" @default.
• W1970352016 modified "2023-09-23" @default.
• W1970352016 title "On the stereochemistry of the Baker's Yeast-mediated reduction of regioisomeric unsaturated aldehydes: Examples of enantioselectivity switch promoted by substrate-engineering" @default.
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• W1970352016 doi "https://doi.org/10.1016/j.molcatb.2012.02.003" @default.
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