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- W1970386130 abstract "The efficient asymmetric preparation of the C 2 -symmetric chiral 1,4-diamine, (1R,25,4R,5S)-1,4-diamino-2,5-dimethylcyclohexane (5), and its salen ligands is described. With the Mitsunobu reaction as the key step, the overall yield of the four-step synthesis of 5 is 45%. The enantioselective alkynylation of meso-epoxides catalyzed by chiral gallium complexes is also achieved." @default.
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- W1970386130 date "2004-06-29" @default.
- W1970386130 modified "2023-10-18" @default.
- W1970386130 title "The Synthesis of New C2-Symmetric Chiral 1,4-Diamino Motif and Application in Catalytic Asymmetric Alkynylation of meso-Epoxides." @default.
- W1970386130 cites W4232105014 @default.
- W1970386130 doi "https://doi.org/10.1002/chin.200426029" @default.
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