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- W1970392850 abstract "Abstract H 4 PO + 3 ions have been generated in a mass spectrometer by proton-transfer to H 3 PO 3 from different Bronsted acids. The proton affinity of H 3 PO 3 has been estimated by bracketing and kinetic methods to be 198.6 ± 2 kcal mol −1 . Gaseous H 4 PO + 3 ions have been structurally assessed by metastable ion kinetic energy (MIKE) and collisionally induced dissociation (CID) mass spectrometry leading to the detection of a single isomeric species. The chemistry of H 2 PO − 3 is characterized by facile addition-elimination reactions leading to formation of polyanions. Species containing up to six P atoms have been detected." @default.
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- W1970392850 date "1994-09-01" @default.
- W1970392850 modified "2023-09-23" @default.
- W1970392850 title "A mass spectrometric study of gaseous H4PO+3 and H2PO−3 ions" @default.
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- W1970392850 doi "https://doi.org/10.1016/0168-1176(94)04022-2" @default.
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