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- W1970418166 abstract "Abstract Temperature dependencies of proton magnetic relaxation times and forms of transversal magnetisation decay in chloroform-d solutions of three liquid crystalline polyesters with fumaroil-bis-oxybenzoate mesogenic units connected by different flexible spacers (CH 2 ) 5 , (CH 2 ) 6 and CH 2 (CH 2 CH 2 O 2 ) 2 CH 2 (poly(R-M5), poly(R-M6) and poly(R-EO2), respectively) are studied in the concentration range 9–20 w/w%. Chemical exchange is shown to influence the form of transversal magnetisation decay and the dependencies of spin—spin relaxation time on the time interval in Curr—Purcell sequence. The rate of exchange is shown to depend on spacer flexibility and evenness, and on molecular mass and concentration. The exchange parameters (life time, chemical shift difference, populations) for poly(R-M6) solutions are estimated, and their dependencies on temperature and concentration are discussed in terms of heterophase fluctuations of local order." @default.
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- W1970418166 date "1998-05-01" @default.
- W1970418166 modified "2023-09-27" @default.
- W1970418166 title "Pulse n.m.r. study of the dynamics of fluctuations of local anisotropy in the solutions of liquid crystalline R-F polymers" @default.
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- W1970418166 doi "https://doi.org/10.1016/s0032-3861(97)00272-3" @default.
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