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- W1970425634 abstract "We have prepared a new insulating film for use on various metals, by oxidizing 2-mercaptobenzimidazole (2-MBI) in alkaline water-methanol solutions. The film formed at copper surface, with additives and under controlled voltage conditions, shows promising anti-corrosion properties in neutral saline conditions. The formation mechanism and structure of the film were investigated on Cu using voltammetric experiments, elemental analyses, infrared spectroscopy and mass spectrometry. In addition to the oxidation of Cu to Cu-(2-MBI) complexes, the oxidation of the pyrrole nitrogen is found to follow 2-MBI dimerization, and involves C–S coupling reactions." @default.
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- W1970425634 date "1998-10-01" @default.
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- W1970425634 title "Characterization and mechanism of direct film formation on a cu electrode through electro-oxidation of 2-mercaptobenzimidazole" @default.
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- W1970425634 doi "https://doi.org/10.1016/s0010-938x(98)00060-2" @default.
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