FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1970430907> ?p ?o ?g. }

• W1970430907 endingPage "1585" @default.
• W1970430907 startingPage "1580" @default.
• W1970430907 abstract "In this work, colloidal zinc sulfide nanocrystals, prepared with selected concentrations of manganese(II) ions in the range of 0−2% and stabilized with a polymeric capping agent, were used in the photocatalytic degradation of 2-chlorophenol in aqueous solutions. Particle sizes for the synthesized nanocrystals were determined using UV−vis absorbance spectroscopy and X-ray diffraction (XRD). UV−vis spectra for all of the synthesized nanocrystals display an excitonic peak at around 290 nm, which corresponds to a particle size of approximately 3 nm, in agreement with the XRD analysis. Photoluminescence emission spectra recorded for undoped ZnS nanocrystals exhibit an emission peak at 460 nm in the spectrum, whereas peaks corresponding to the dopant ion are red-shifted to 590 nm. With increasing addition of the dopant ion, the area of the peak at 460 nm first increases and then decreases for higher dopant concentrations, whereas the area of the peak at 590 nm increases. This finding clearly indicates that the presence of the dopant ion alters the electronic states of the nanocrystals, which, in turn, affects the photocatalytic properties of the colloidal nanocrystals. Apparent rate constants for the photodegradation of 2-chlorophenol in aqueous solution utilizing undoped and doped colloidal ZnS nanocrystals were calculated using pseudo-first-order kinetic analysis. As the dopant concentration used during synthesis was increased, the apparent rate constants increased initially and then decreased. Results from kinetic experiments performed after nitrogen purging showed a decrease in the apparent rate constant, suggesting that the reaction mechanism involves a reactive oxygen species such as superoxide. Taken together, these results provide further insight into the effects of dopants on the activity of colloidal semiconductor nanocrystals employed as photocatalysts in environmental remediation applications." @default.
• W1970430907 created "2016-06-24" @default.
• W1970430907 creator A5053076537 @default.
• W1970430907 creator A5064594365 @default.
• W1970430907 creator A5078817701 @default.
• W1970430907 date "2010-01-04" @default.
• W1970430907 modified "2023-09-26" @default.
• W1970430907 title "Dopant Effects on the Photocatalytic Activity of Colloidal Zinc Sulfide Semiconductor Nanocrystals for the Oxidation of 2-Chlorophenol" @default.
• W1970430907 cites W1964782890 @default.
• W1970430907 cites W1975714039 @default.
• W1970430907 cites W1975822685 @default.
• W1970430907 cites W1979609139 @default.
• W1970430907 cites W1993289359 @default.
• W1970430907 cites W1994328000 @default.
• W1970430907 cites W1994548621 @default.
• W1970430907 cites W1995720737 @default.
• W1970430907 cites W1997926068 @default.
• W1970430907 cites W2000052651 @default.
• W1970430907 cites W2004905708 @default.
• W1970430907 cites W2007766470 @default.
• W1970430907 cites W2012589623 @default.
• W1970430907 cites W2019643523 @default.
• W1970430907 cites W2022831883 @default.
• W1970430907 cites W2024354170 @default.
• W1970430907 cites W2027149576 @default.
• W1970430907 cites W2029130502 @default.
• W1970430907 cites W2030857214 @default.
• W1970430907 cites W2042463038 @default.
• W1970430907 cites W2046196469 @default.
• W1970430907 cites W2056911181 @default.
• W1970430907 cites W2062651013 @default.
• W1970430907 cites W2064368798 @default.
• W1970430907 cites W2065257857 @default.
• W1970430907 cites W2071453428 @default.
• W1970430907 cites W2074385540 @default.
• W1970430907 cites W2076268931 @default.
• W1970430907 cites W2078301208 @default.
• W1970430907 cites W2085383676 @default.
• W1970430907 cites W2086210408 @default.
• W1970430907 cites W2087002485 @default.
• W1970430907 cites W2089966653 @default.
• W1970430907 cites W2143546017 @default.
• W1970430907 doi "https://doi.org/10.1021/jp907061d" @default.
• W1970430907 hasPublicationYear "2010" @default.
• W1970430907 type Work @default.
• W1970430907 sameAs 1970430907 @default.
• W1970430907 citedByCount "22" @default.
• W1970430907 countsByYear W19704309072012 @default.
• W1970430907 countsByYear W19704309072013 @default.
• W1970430907 countsByYear W19704309072014 @default.
• W1970430907 countsByYear W19704309072015 @default.
• W1970430907 countsByYear W19704309072016 @default.
• W1970430907 countsByYear W19704309072018 @default.
• W1970430907 countsByYear W19704309072019 @default.
• W1970430907 countsByYear W19704309072020 @default.
• W1970430907 countsByYear W19704309072021 @default.
• W1970430907 countsByYear W19704309072023 @default.
• W1970430907 crossrefType "journal-article" @default.
• W1970430907 hasAuthorship W1970430907A5053076537 @default.
• W1970430907 hasAuthorship W1970430907A5064594365 @default.
• W1970430907 hasAuthorship W1970430907A5078817701 @default.
• W1970430907 hasConcept C113196181 @default.
• W1970430907 hasConcept C121332964 @default.
• W1970430907 hasConcept C147789679 @default.
• W1970430907 hasConcept C148898269 @default.
• W1970430907 hasConcept C161790260 @default.
• W1970430907 hasConcept C162847780 @default.
• W1970430907 hasConcept C171250308 @default.
• W1970430907 hasConcept C175854130 @default.
• W1970430907 hasConcept C178790620 @default.
• W1970430907 hasConcept C179104552 @default.
• W1970430907 hasConcept C184651966 @default.
• W1970430907 hasConcept C185592680 @default.
• W1970430907 hasConcept C187530423 @default.
• W1970430907 hasConcept C191897082 @default.
• W1970430907 hasConcept C191952053 @default.
• W1970430907 hasConcept C192562407 @default.
• W1970430907 hasConcept C2779219880 @default.
• W1970430907 hasConcept C49040817 @default.
• W1970430907 hasConcept C535196362 @default.
• W1970430907 hasConcept C57863236 @default.
• W1970430907 hasConcept C62520636 @default.
• W1970430907 hasConcept C65165184 @default.
• W1970430907 hasConcept C93391505 @default.
• W1970430907 hasConceptScore W1970430907C113196181 @default.
• W1970430907 hasConceptScore W1970430907C121332964 @default.
• W1970430907 hasConceptScore W1970430907C147789679 @default.
• W1970430907 hasConceptScore W1970430907C148898269 @default.
• W1970430907 hasConceptScore W1970430907C161790260 @default.
• W1970430907 hasConceptScore W1970430907C162847780 @default.
• W1970430907 hasConceptScore W1970430907C171250308 @default.
• W1970430907 hasConceptScore W1970430907C175854130 @default.
• W1970430907 hasConceptScore W1970430907C178790620 @default.
• W1970430907 hasConceptScore W1970430907C179104552 @default.
• W1970430907 hasConceptScore W1970430907C184651966 @default.
• W1970430907 hasConceptScore W1970430907C185592680 @default.
• W1970430907 hasConceptScore W1970430907C187530423 @default.
• W1970430907 hasConceptScore W1970430907C191897082 @default.

• next