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- W1970432856 abstract "A bimetallic Pd-promoted gold catalyst with mesoporous silica nanoparticles (MSNs) as support, PdAu/MSN, was prepared by an impregnation–hydrogen reduction method, and its catalysis for the base-free oxidation of benzyl alcohol was investigated. It was found that adding a small amount of Pd, with a Pd/Au atomic ratio as low as 0.05/1, can significantly decrease the size of the gold particles and thereby remarkably enhance the catalyst's activity for aerobatic oxidation. At the optimal Pd/Au atomic ratio of 0.2/1, the catalyst Pd0.2Au/MSN showed 8 times and 3 times higher activity than the monometallic catalysts Au/MSN and Pd/MSN, respectively. The prepared catalysts were comprehensively characterized by XRD, DRUV-vis, TEM, XPS, and H2-TPR to correlate the enhanced activity with the promotional effect induced by adding Pd." @default.
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- W1970432856 date "2013-08-01" @default.
- W1970432856 modified "2023-10-15" @default.
- W1970432856 title "An effective Pd-promoted gold catalyst supported on mesoporous silica particles for the oxidation of benzyl alcohol" @default.
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- W1970432856 doi "https://doi.org/10.1016/j.apcatb.2013.04.029" @default.
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