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- W1970437823 abstract "The far-infrared spectra of crystalline polyvinylidene fluoride (form II) has been obtained at temperatures ranging from 13 to 373 °K. The results show four lines at 53, 85, 102, and 175 cm−1. The latter three lines are assigned to intramolecular vibrations of a single TGTG′ chain. The 53 cm−1 line is attributed to a rotatory lattice mode predicted by a factor group analysis of space group P21/c and substantiated by both crystallinity studies and by the investigation of frequency shifts and intensity changes with decreasing temperature. The latter is consistent with a contraction of the unit cell at low temperatures and an increasing intermolecular interaction between the two chains in the unit cell." @default.
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- W1970437823 date "1973-10-01" @default.
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- W1970437823 title "Low frequency vibrations in polyvinylidene fluoride (form II)" @default.
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- W1970437823 doi "https://doi.org/10.1063/1.1680540" @default.
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