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• W1970452109 abstract "Changes in ionic composition (i.e., doping) accompany changes in the redox level of conducting polymers such as polypyrrole. These processes are of paramount interest because they often control the polymer's charge capacity and, more importantly, its rates of oxidation and reduction (i.e., charge and discharge). The most commonly used approaches for studying polymer doping are either ex situ techniques (e.g., elemental analysis, X-ray photoelectron spectroscopy) or nonspecific techniques (e.g., electrochemical quartz crystal microgravimetry). We have developed a paradigm whereby rotated ring−disk electrode (RRDE) voltammetry can be used to quantitatively measure both anion and cation fluxes, in situ, across the conducting polymer−solution interface. This can be accomplished in real time under operational electrochemical conditions. Herein we report studies where we use RRDE voltammetry to investigate the doping behavior of electrochemically grown films of polypyrrole which are in contact with a range of different electrolyte solutions." @default.
• W1970452109 created "2016-06-24" @default.
• W1970452109 creator A5003394848 @default.
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• W1970452109 date "2000-07-08" @default.
• W1970452109 modified "2023-09-27" @default.
• W1970452109 title "Quantitative in Situ Studies of Ionic Doping of Polypyrrole Employing Rotated Ring−Disk Electrode Voltammetry" @default.
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• W1970452109 doi "https://doi.org/10.1021/cm0000189" @default.
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