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• W1970460469 abstract "Binary systems with water and levo- or dextro-2,3-butanediol have a much larger glass-forming tendency on cooling and stability of the wholly amorphous state on warming, for same solute contents, than any previously studied binary and ternary systems, including all those containing 1,2-propanediol. For the first time, complete vitrification could be obtained with only 30% (w/w) solute. With 35% (w/w) of these isomers, a cooling rate of 20 °C/min is sufficient to obtain complete vitrification, compared with 300 °C/min with 35% 1,2-propanediol in water. The warming rate necessary to avoid ice crystallization from the wholly amorphous solution is about 104 °C/min, compared with about 108 °C/min with 35% 1,2-propanediol. The aqueous solutions of the racemic mixtures of these two isomers have almost the same properties as those of separate isomers and are as interesting. These solutes could perhaps allow the solution of the problem of organ cryopreservation by vitrification." @default.
• W1970460469 created "2016-06-24" @default.
• W1970460469 creator A5014713479 @default.
• W1970460469 date "1990-02-01" @default.
• W1970460469 modified "2023-09-25" @default.
• W1970460469 title "Levo- and dextro-2,3-Butanediol and their racemic mixture: Very efficient solutes for vitrification" @default.
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• W1970460469 doi "https://doi.org/10.1016/0011-2240(90)90052-6" @default.
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