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- W1970487352 abstract "A new method for laser-enhanced ionization detection of mercury atoms in an inert gas atmosphere is described. The method, which is based on the avalanche amplification of the signal resulting from the ionization from a selected Rydberg level reached by a three-step laser excitation of mercury vapor in a simple quartz cell, can be applied to the determination of this element in various matrices by the use of conventional cold atomization techniques. The overall (collisional + photo) ionization efficiency is investigated at different temperatures, and the avalanche amplification effect is reported for Ar and P-10 gases at atmospheric pressure. It is shown that the amplified signal is related to the number of charges produced in the laser-irradiated volume. Under amplifier noise-limited conditions, a detection limit of ∼15 Hg atoms/laser pulse in the interaction region is estimated." @default.
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- W1970487352 date "1997-07-01" @default.
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- W1970487352 title "Laser-Enhanced Ionization of Mercury Atoms in an Inert Atmosphere with Avalanche Amplification of the Signal" @default.
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- W1970487352 doi "https://doi.org/10.1021/ac9702148" @default.
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