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- W1970531627 abstract "Abstract Microwave spectra of methylpropargylether and its nine isotopically substituted species were measured. The plausible structure of this molecule was determined from the observed moments of inertia. The r s structural parameters of the OCH 3 part of the molecule could be obtained and were compared with the corresponding parameters of the analogous molecules. The dipole moment and its direction in the molecule were determined by Stark-effect measurements. The barrier to internal rotation of the methyl group was determined from the A - E splittings of the spectra reported by K. M. Marstokk and H. Mollendal ( J. Mol. Struct. 32, 191–202 (1976) taking into account the coupling effect of the skeletal torsion." @default.
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- W1970531627 date "1980-12-01" @default.
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- W1970531627 title "Microwave spectrum, structure, dipole moment, and internal rotation of methylpropargylether" @default.
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- W1970531627 doi "https://doi.org/10.1016/0022-2852(80)90028-4" @default.
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