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• W1970540510 abstract "Abstract The Raman spectra of nanocrystalline PbTi 0.75 Zr 0.25 O 3 show that its perovskite phase occurred at a higher crystallization temperature during its sol-gel process than the perovskite PbTiO 3 phase. The effects of grain size on the ferroelectric phase transition and the soft mode have been investigated. The phase transition temperature T c is shifted to a lower temperature with decreasing grain size. The possibility that the additional mode occurring in the low frequency Raman spectra might be due to zone boundary transverse acoustical phonons which couple to the q ∼ 0 soft TO phonon mode is confirmed. The Raman spectra, as a function of pressure, reveal that the phase transition may be correlated with Diffuse Phase Transition (DPT)." @default.
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• W1970540510 date "1994-05-01" @default.
• W1970540510 modified "2023-09-27" @default.
• W1970540510 title "Influence of grain size on the soft mode and the phase transition in the nanocrystalline PbTi1−xZrxO3 system" @default.
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• W1970540510 doi "https://doi.org/10.1016/0022-3697(94)90168-6" @default.
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