FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1970540671> ?p ?o ?g. }

• W1970540671 endingPage "7618" @default.
• W1970540671 startingPage "7612" @default.
• W1970540671 abstract "Chromium-substituted LiMn1-xCrxO2 (0 ≤ x ≤ 0.15) oxides have been prepared by the ion-exchange reaction between α-NaMn1-xCrxO2 and LiBr. From the X-ray diffraction and infrared spectroscopic analyses, all of the present layered compounds are found to be crystallized with monoclinic structure. Additionally, the nitrogen adsorption−desorption isotherm measurements indicate a decrease in crystallite size induced by the replacement of Mn with Cr. According to the electrochemical measurements, the Cr-substituted compounds exhibit better electrochemical performance than the pristine LiMnO2. The effects of chromium substitution on the chemical bonding nature of LiMn1-xCrxO2 have been investigated by performing X-ray absorption spectroscopic (XAS) analyses. The Cr K-edge XAS results presented here clarify that the trivalent chromium ions are stabilized in the octahedral site of the (Mn,Cr)O2 layer before and after the electrochemical charge−discharge process. From the extended X-ray absorption fine structure analyses at the Mn K-edge, it becomes clear that the substitution of manganese with chromium gives rise to a shortening of the Mn−O bonds, leading to the stabilization of Mn in the octahedral site. On the basis of the present experimental findings, we suggest that the superior electrochemical performance of LiMn1-xCrxO2 can be attributed to the enhanced stability of the layered manganese oxide lattice because of the presence of a chromium ion in the octahedral site of the transition metal oxide layer, which hinders the migration of manganese ions into the interlayer lithium sites." @default.
• W1970540671 created "2016-06-24" @default.
• W1970540671 creator A5048465218 @default.
• W1970540671 creator A5055569860 @default.
• W1970540671 creator A5057212239 @default.
• W1970540671 creator A5065443386 @default.
• W1970540671 date "2000-07-25" @default.
• W1970540671 modified "2023-09-25" @default.
• W1970540671 title "Effects of Chromium Substitution on the Chemical Bonding Nature and Electrochemical Performance of Layered Lithium Manganese Oxide" @default.
• W1970540671 cites W1493202635 @default.
• W1970540671 cites W1785856039 @default.
• W1970540671 cites W1966440289 @default.
• W1970540671 cites W1981236557 @default.
• W1970540671 cites W1983896311 @default.
• W1970540671 cites W1984654822 @default.
• W1970540671 cites W2019857813 @default.
• W1970540671 cites W2021327362 @default.
• W1970540671 cites W2027937473 @default.
• W1970540671 cites W2033993837 @default.
• W1970540671 cites W2041773142 @default.
• W1970540671 cites W2056461577 @default.
• W1970540671 cites W2060142904 @default.
• W1970540671 cites W2073116686 @default.
• W1970540671 cites W2080445869 @default.
• W1970540671 cites W2124311450 @default.
• W1970540671 cites W2133751550 @default.
• W1970540671 cites W2142987519 @default.
• W1970540671 cites W2167590372 @default.
• W1970540671 cites W2460714828 @default.
• W1970540671 cites W2949086998 @default.
• W1970540671 cites W389343229 @default.
• W1970540671 doi "https://doi.org/10.1021/jp0016176" @default.
• W1970540671 hasPublicationYear "2000" @default.
• W1970540671 type Work @default.
• W1970540671 sameAs 1970540671 @default.
• W1970540671 citedByCount "52" @default.
• W1970540671 countsByYear W19705406712012 @default.
• W1970540671 countsByYear W19705406712013 @default.
• W1970540671 countsByYear W19705406712015 @default.
• W1970540671 countsByYear W19705406712016 @default.
• W1970540671 countsByYear W19705406712017 @default.
• W1970540671 countsByYear W19705406712019 @default.
• W1970540671 countsByYear W19705406712020 @default.
• W1970540671 countsByYear W19705406712021 @default.
• W1970540671 countsByYear W19705406712022 @default.
• W1970540671 countsByYear W19705406712023 @default.
• W1970540671 crossrefType "journal-article" @default.
• W1970540671 hasAuthorship W1970540671A5048465218 @default.
• W1970540671 hasAuthorship W1970540671A5055569860 @default.
• W1970540671 hasAuthorship W1970540671A5057212239 @default.
• W1970540671 hasAuthorship W1970540671A5065443386 @default.
• W1970540671 hasConcept C106773901 @default.
• W1970540671 hasConcept C115624301 @default.
• W1970540671 hasConcept C119824511 @default.
• W1970540671 hasConcept C121332964 @default.
• W1970540671 hasConcept C134018914 @default.
• W1970540671 hasConcept C147789679 @default.
• W1970540671 hasConcept C150394285 @default.
• W1970540671 hasConcept C161790260 @default.
• W1970540671 hasConcept C17525397 @default.
• W1970540671 hasConcept C179104552 @default.
• W1970540671 hasConcept C185592680 @default.
• W1970540671 hasConcept C191897082 @default.
• W1970540671 hasConcept C192562407 @default.
• W1970540671 hasConcept C198819137 @default.
• W1970540671 hasConcept C2778541603 @default.
• W1970540671 hasConcept C2779851234 @default.
• W1970540671 hasConcept C511782168 @default.
• W1970540671 hasConcept C52859227 @default.
• W1970540671 hasConcept C528890316 @default.
• W1970540671 hasConcept C55493867 @default.
• W1970540671 hasConcept C62284982 @default.
• W1970540671 hasConcept C62520636 @default.
• W1970540671 hasConcept C71924100 @default.
• W1970540671 hasConcept C8010536 @default.
• W1970540671 hasConceptScore W1970540671C106773901 @default.
• W1970540671 hasConceptScore W1970540671C115624301 @default.
• W1970540671 hasConceptScore W1970540671C119824511 @default.
• W1970540671 hasConceptScore W1970540671C121332964 @default.
• W1970540671 hasConceptScore W1970540671C134018914 @default.
• W1970540671 hasConceptScore W1970540671C147789679 @default.
• W1970540671 hasConceptScore W1970540671C150394285 @default.
• W1970540671 hasConceptScore W1970540671C161790260 @default.
• W1970540671 hasConceptScore W1970540671C17525397 @default.
• W1970540671 hasConceptScore W1970540671C179104552 @default.
• W1970540671 hasConceptScore W1970540671C185592680 @default.
• W1970540671 hasConceptScore W1970540671C191897082 @default.
• W1970540671 hasConceptScore W1970540671C192562407 @default.
• W1970540671 hasConceptScore W1970540671C198819137 @default.
• W1970540671 hasConceptScore W1970540671C2778541603 @default.
• W1970540671 hasConceptScore W1970540671C2779851234 @default.
• W1970540671 hasConceptScore W1970540671C511782168 @default.
• W1970540671 hasConceptScore W1970540671C52859227 @default.
• W1970540671 hasConceptScore W1970540671C528890316 @default.
• W1970540671 hasConceptScore W1970540671C55493867 @default.
• W1970540671 hasConceptScore W1970540671C62284982 @default.
• W1970540671 hasConceptScore W1970540671C62520636 @default.
• W1970540671 hasConceptScore W1970540671C71924100 @default.

• next