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- W1970592368 abstract "With a view to obtaining a clearer understanding of several generalizations concerning bond strength, calculations on a number of model molecules have been made. The Heitler-London-Sugiura treatment has been extended to systems of two nuclei and two electrons in which the nuclear charges are less than or greater than + l e , and in which they may or may not be equal. In this way the screening effect of electrons which are not involved in the bond, as in a real molecule, has been roughly simulated. The effect of adding ionic terms and minimizing with respect to them has been studied in a number of cases. The results obtained help to resolve the apparent contradiction between Pauling's adjacent charge rule and Gordy’s rule connecting electronegativities and bond strength. They also suggest that the importance of changes in internuclear repulsion is greater, and that of changes in ionic contributions is less, in causing the relative stabilization of molecules with unequal centres, than has previously been supposed. They lead, however, to an expression for tins stabilization which is similar in form to that evolved by Pauling, and so provide a new basis for interpreting atomic electronegativities. Finally, they reconcile in large measure the latter relation with Walsh’s views concerning bond polarity and bond strength." @default.
- W1970592368 created "2016-06-24" @default.
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- W1970592368 date "1951-06-07" @default.
- W1970592368 modified "2023-09-29" @default.
- W1970592368 title "Covalency, electrovalency and electronegativity" @default.
- W1970592368 doi "https://doi.org/10.1098/rspa.1951.0098" @default.
- W1970592368 hasPublicationYear "1951" @default.
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