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- W1970596435 abstract "Spontaneous interconfiguration fluctuations have been detected in TmTe and TmSe by x-ray photoemission. The resulting instantaneous picture of the Tm ions fluctuating between the divalent and trivalent state within the same environment allows a direct measurement of the magnitude of the Coulomb correlation energy, ${U}_{mathrm{eff}}$. Spontaneous interconfiguration fluctuations are shown also to affect the binding energies of core levels within the same rare-earth ion, resulting in a chemical shift of 3.5 ifmmodepmelsetextpmfi{} 0.1 eV for the Tm ($5p$) core levels." @default.
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- W1970596435 date "1974-04-22" @default.
- W1970596435 modified "2023-09-26" @default.
- W1970596435 title "Spontaneous Interconfiguration Fluctuations in the Tm Monochalcogenides" @default.
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- W1970596435 doi "https://doi.org/10.1103/physrevlett.32.885" @default.
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