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• W1970597630 abstract "Abstract The molecular structure and conformational composition of trans -1,2-dimethylcyclopentane have been studied at nozzle temperatures of 298 K and 448 K by gas-phase electron diffraction. The molecule is found to be pseudorotating with a flat minimum at the diequatorial form. The enthalpy difference between the diaxial and the diequatorial forms is found to be about 1.9 kcal mol −1 . Least squares analysis of the pseudorotational model results in the following bond distances ( r g ) and valence angles (∠ α ): r (CH) = 1.099(6) A, r (CC) = 1.540(2) A, ∠CCC=115(1)°, ∠CCH = 114(1)°, ∠CC m H = 108(2)° and q = 0.33(3) A." @default.
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• W1970597630 date "1991-06-01" @default.
• W1970597630 modified "2023-09-27" @default.
• W1970597630 title "The molecular structure and pseudorotational motion of trans-1,2-dimethylcyclopentane as determined by gas-phase electron diffraction" @default.
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• W1970597630 doi "https://doi.org/10.1016/0022-2860(91)80131-m" @default.
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