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- W1970607207 abstract "Abstract A γ-irradiated in bulk PP was investigated. It was swollen and partially dissolved in boiling xylene. After this it was crystallised by evaporation of the solvent. The supermolecular structure was characterised by means of microscopy and SALS. It was suggested that the crystallisation proceeds from viscous melts. The melts contained soluble and insoluble parts. The insoluble part consisted of micro- and macrogel of crosslinked PP with low and irregular crosslinking density. The spherulites and crystallites had a high defect density. They were built up of α-γ dendrite twins. It is shown that the rate of primary nucleation increases sharply at about 0.1 MGy, remaining further constant. The rates of the secondary nucleation and lamellar growth decrease sharply with dose. It has been suggested that the rates of primary and secondary nucleation depend not only on the number of radiation defects, but also on the direction of the spreading of the energy released by the interaction of γ quants with the crystal lattice of the polymer." @default.
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- W1970607207 date "1991-01-01" @default.
- W1970607207 modified "2023-09-26" @default.
- W1970607207 title "Morphology of gamma-irradiated polypropylene gels crystallised from xylene solution—1. Optical microscopy and sals" @default.
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- W1970607207 doi "https://doi.org/10.1016/1359-0197(91)90146-s" @default.
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