FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1970608081> ?p ?o ?g. }

• W1970608081 endingPage "3263" @default.
• W1970608081 startingPage "3256" @default.
• W1970608081 abstract "Two kinds of binucleating ligands, 2,6-bis(arylimino)phenoxy (1a: aryl = 2,6-diisopropylphenyl; 1b: aryl = 2,4,6-tri-tert-butylphenyl) and 3,6-bis(imino(2,6-diisopropylphenyl))pyridazine (2), were prepared, and their proximal complexation with two palladium atoms was studied. Treatment of the sodium compounds of 1a,b with 2 equiv of PdCl2(PhCN)2 and PdMeCl(cod) afforded the corresponding homobimetallic complexes, [2,6-bis(arylimino)phenoxy][RPd(μ-Cl)PdR] (4a: R = Cl, aryl = 2,6-diisopropylphenyl; 4b: R = Cl, aryl = 2,4,6-tri-tert-butylphenyl; 7a: R = Me, aryl = 2,6-diisopropylphenyl; 7b: R = Me, aryl = 2,4,6-tri-tert-butylphenyl), whose structures were characterized spectroscopically and crystallographically. In the reaction between the sodium compound of 1a with 1 equiv of PdCl2(PhCN)2, we detected the NaCl adduct of mononuclear palladium species 5a, which, upon release of NaCl, formed a dimeric complex, ([2,6-bis(2,6-diisopropylphenylimino)phenoxy](PdCl])2 (4a), as confirmed by X-ray analysis. Complexation of 2 with 2 equiv of PdCl2(PhCN)2 and PdMeCl(cod) in the presence of 1 equiv of AgBF4 resulted in the formation of the corresponding cationic complexes ([3,6-bis(imino(2,6-diisopropylphenyl))pyridazine][RPd(μ-Cl)PdR])(BF4) (9a: R = Cl; 9b: R = Me), whose RPd(μ-Cl)PdR skeletons (R = Cl and Me) were revealed spectroscopically and crystallographically." @default.
• W1970608081 created "2016-06-24" @default.
• W1970608081 creator A5020162295 @default.
• W1970608081 creator A5028694488 @default.
• W1970608081 creator A5029903238 @default.
• W1970608081 creator A5033927608 @default.
• W1970608081 creator A5064250684 @default.
• W1970608081 creator A5069114564 @default.
• W1970608081 date "2009-04-24" @default.
• W1970608081 modified "2023-10-17" @default.
• W1970608081 title "Synthesis and Characterization of Proximal Dinuclear Complexes of Palladium Supported by 2,6-Bis(arylimino)phenoxy (aryl = 2,6-diisopropylphenyl and 2,4,6-tri-<i>tert</i>-butylphenyl) and 3,6-Bis(imino(2,6-diisopropylphenyl))pyridazine Ligands" @default.
• W1970608081 cites W1963812262 @default.
• W1970608081 cites W1966367741 @default.
• W1970608081 cites W1967558203 @default.
• W1970608081 cites W1969860780 @default.
• W1970608081 cites W1971322951 @default.
• W1970608081 cites W1975217371 @default.
• W1970608081 cites W1977523770 @default.
• W1970608081 cites W1979858943 @default.
• W1970608081 cites W1983190751 @default.
• W1970608081 cites W1983329470 @default.
• W1970608081 cites W1984592575 @default.
• W1970608081 cites W1989557333 @default.
• W1970608081 cites W1994139905 @default.
• W1970608081 cites W1995166961 @default.
• W1970608081 cites W1997354567 @default.
• W1970608081 cites W1998170765 @default.
• W1970608081 cites W1999961085 @default.
• W1970608081 cites W2001932980 @default.
• W1970608081 cites W2003448010 @default.
• W1970608081 cites W2006118631 @default.
• W1970608081 cites W2010300660 @default.
• W1970608081 cites W2010546696 @default.
• W1970608081 cites W2013459858 @default.
• W1970608081 cites W2013733015 @default.
• W1970608081 cites W2016271477 @default.
• W1970608081 cites W2017843076 @default.
• W1970608081 cites W2018731225 @default.
• W1970608081 cites W2019696103 @default.
• W1970608081 cites W2025667117 @default.
• W1970608081 cites W2026861912 @default.
• W1970608081 cites W2027018043 @default.
• W1970608081 cites W2028444801 @default.
• W1970608081 cites W2028902552 @default.
• W1970608081 cites W2029140525 @default.
• W1970608081 cites W2029243364 @default.
• W1970608081 cites W2029694100 @default.
• W1970608081 cites W2030260780 @default.
• W1970608081 cites W2030841140 @default.
• W1970608081 cites W2039881521 @default.
• W1970608081 cites W2041987548 @default.
• W1970608081 cites W2047131428 @default.
• W1970608081 cites W2049679247 @default.
• W1970608081 cites W2050064155 @default.
• W1970608081 cites W2054696863 @default.
• W1970608081 cites W2055997312 @default.
• W1970608081 cites W2059020082 @default.
• W1970608081 cites W2060567333 @default.
• W1970608081 cites W2066370105 @default.
• W1970608081 cites W2067434165 @default.
• W1970608081 cites W2074880155 @default.
• W1970608081 cites W2079055375 @default.
• W1970608081 cites W2084223211 @default.
• W1970608081 cites W2087919688 @default.
• W1970608081 cites W2088221767 @default.
• W1970608081 cites W2090229189 @default.
• W1970608081 cites W2091621757 @default.
• W1970608081 cites W2095133124 @default.
• W1970608081 cites W2095777777 @default.
• W1970608081 cites W2099352584 @default.
• W1970608081 cites W2114858685 @default.
• W1970608081 cites W2122127953 @default.
• W1970608081 cites W2124537505 @default.
• W1970608081 cites W2125082952 @default.
• W1970608081 cites W2132218304 @default.
• W1970608081 cites W2133449402 @default.
• W1970608081 cites W2156101148 @default.
• W1970608081 cites W2160489485 @default.
• W1970608081 cites W2160848311 @default.
• W1970608081 cites W2171781058 @default.
• W1970608081 cites W2949756159 @default.
• W1970608081 cites W2950507086 @default.
• W1970608081 cites W2950664052 @default.
• W1970608081 cites W2951544323 @default.
• W1970608081 cites W2951747989 @default.
• W1970608081 cites W2952024323 @default.
• W1970608081 cites W2953077307 @default.
• W1970608081 cites W2953195867 @default.
• W1970608081 cites W3004939862 @default.
• W1970608081 cites W1984684573 @default.
• W1970608081 doi "https://doi.org/10.1021/om900043u" @default.
• W1970608081 hasPublicationYear "2009" @default.
• W1970608081 type Work @default.
• W1970608081 sameAs 1970608081 @default.
• W1970608081 citedByCount "20" @default.
• W1970608081 countsByYear W19706080812012 @default.
• W1970608081 countsByYear W19706080812014 @default.
• W1970608081 countsByYear W19706080812015 @default.

• next