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- W1970644706 abstract "Abstract Derivatives of a new diaminotrideoxy- d - ribo -hexopyranose, a component of the antibiotic tobramycin, have been prepared by addition of the elements of hydrazoic acid to the α, β-unsaturated ketone 8 . After 5 min only the kinetically favored product 13 was observed, which is gradually transformed into the thermodynamically more-stable substance 20 . The equilibrium mixture after 5 hours contained d - erythro and d - threo isomers 20 and 13 in the ratio 6:4 The d - erythro azide 20 was converted into the derivatives of di- N -acetyl tobrosamine." @default.
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- W1970644706 date "1977-01-01" @default.
- W1970644706 modified "2023-09-26" @default.
- W1970644706 title "Synthese de derives de la tobrosamine par addition d'acide hydrazoique sur un systeme enonique dans la serie hydrate de carbone" @default.
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- W1970644706 doi "https://doi.org/10.1016/0040-4020(77)80209-3" @default.
- W1970644706 hasPublicationYear "1977" @default.
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