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- W1970715431 abstract "Abstract Water dispersible Zn(1−x)MnxS solid solution photocatalysts stabilized with l -aspartic acid were synthesized by coprecipitation. Their photocatalytic activity was evaluated using methylene blue as a model pollutant. X-ray diffraction and Raman spectroscopy indicated the catalysts had a cubic crystal structure. The gradual increase in zinc sulphide (ZnS) lattice constant with increasing Mn2+ dopant concentration was due to the high ionic radius of Mn2+. Raman spectra exhibited two peaks at 260 and 345 cm−1. Ultraviolet–visible absorption spectra of the catalysts exhibited a strong excitonic peak at 270 nm, which was blue shifted compared with that of bulk ZnS (340 nm). This was attributed to quantum confinement and coupling effects. The hydrophilic l -aspartic acid on the photocatalyst surface had a positive effect on photocatalytic activity. The effects of dye and dopant concentrations on photocatalytic activity were investigated." @default.
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- W1970715431 date "2014-04-01" @default.
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- W1970715431 title "Investigation of photocatalytic behavior of l-aspartic acid stabilized Zn(1−x)MnxS solid solutions on methylene blue" @default.
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- W1970715431 doi "https://doi.org/10.1016/j.apcata.2014.02.001" @default.
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