FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1970740618> ?p ?o ?g. }

• W1970740618 endingPage "258" @default.
• W1970740618 startingPage "248" @default.
• W1970740618 abstract "A temporal analysis of products (TAP) reactor was used to study relationships between the mechanism of direct N2O decomposition over metal-loaded zeolites and their resulting activity. Rh-ZSM-5 (prepared by incipient wetness) and Fe-ZSM-5 (prepared by liquid-ion exchange) were chosen as prototypic catalysts displaying low (<550 K) and high (>650 K) temperature activity, respectively. Transient studies at the same contact time revealed the higher activity of Rh-ZSM-5 below 623 K and significantly stronger N2O adsorption over Rh species than over Fe species in the zeolites. Several microkinetic models were applied for simultaneous fitting the transient responses of N2O, N2, and O2. Classical reaction schemes failed to describe the experimental data. The preferred models of N2O decomposition over Rh-ZSM-5 and Fe-ZSM-5 differ in the reaction pathways of O2 formation. For both catalysts, free active metal sites (*) and those occupied by monoatomic oxygen species (*-O) from N2O participate in the decomposition of gas-phase N2O. Gas-phase O2 is formed directly on N2O interaction with *-O over Rh-ZSM-5, whereas the latter reaction over Fe-ZSM-5 leads to a surface bi-atomic oxygen species (O-*-O), followed by its transformation to *-O2. The latter species desorbs as molecular oxygen. Comparison of ion-exchanged and steam-activated Fe-ZSM-5 [J. Phys. Chem. B 110 (2006) 22586] revealed that the reaction mechanism is independent of the iron constitution induced by the preparation and activation routes, despite important differences in catalytic activity. Our quantitative microkinetic analysis demonstrated that both the stronger reversible N2O adsorption and, most importantly, the faster desorption of O2 are distinctive mechanistic features of Rh-ZSM-5, likely indicating its high de-N2O activity." @default.
• W1970740618 created "2016-06-24" @default.
• W1970740618 creator A5007349453 @default.
• W1970740618 creator A5007424456 @default.
• W1970740618 creator A5034626467 @default.
• W1970740618 creator A5056500440 @default.
• W1970740618 date "2008-06-10" @default.
• W1970740618 modified "2023-10-16" @default.
• W1970740618 title "Mechanistic origin of the different activity of Rh-ZSM-5 and Fe-ZSM-5 in N2O decomposition" @default.
• W1970740618 cites W138030918 @default.
• W1970740618 cites W1552013303 @default.
• W1970740618 cites W1964460137 @default.
• W1970740618 cites W1966335864 @default.
• W1970740618 cites W1986322451 @default.
• W1970740618 cites W1988546486 @default.
• W1970740618 cites W1988555624 @default.
• W1970740618 cites W1998399264 @default.
• W1970740618 cites W2000836282 @default.
• W1970740618 cites W2002735905 @default.
• W1970740618 cites W2004160878 @default.
• W1970740618 cites W2005534475 @default.
• W1970740618 cites W2007350418 @default.
• W1970740618 cites W2011254969 @default.
• W1970740618 cites W2013488178 @default.
• W1970740618 cites W2018708385 @default.
• W1970740618 cites W2020179282 @default.
• W1970740618 cites W2020761866 @default.
• W1970740618 cites W2022884715 @default.
• W1970740618 cites W2030401400 @default.
• W1970740618 cites W2031565508 @default.
• W1970740618 cites W2036044786 @default.
• W1970740618 cites W2048431332 @default.
• W1970740618 cites W2048870515 @default.
• W1970740618 cites W2050296155 @default.
• W1970740618 cites W2053289371 @default.
• W1970740618 cites W2053608884 @default.
• W1970740618 cites W2055709668 @default.
• W1970740618 cites W2057219172 @default.
• W1970740618 cites W2061068743 @default.
• W1970740618 cites W2062788842 @default.
• W1970740618 cites W2063896065 @default.
• W1970740618 cites W2067618556 @default.
• W1970740618 cites W2070040769 @default.
• W1970740618 cites W2070779353 @default.
• W1970740618 cites W2076780983 @default.
• W1970740618 cites W2077556786 @default.
• W1970740618 cites W2080263657 @default.
• W1970740618 cites W2083109633 @default.
• W1970740618 cites W2085633029 @default.
• W1970740618 cites W2091450136 @default.
• W1970740618 cites W2105042418 @default.
• W1970740618 cites W2110733852 @default.
• W1970740618 cites W2116746109 @default.
• W1970740618 cites W2139926595 @default.
• W1970740618 cites W2168128161 @default.
• W1970740618 cites W2168130998 @default.
• W1970740618 doi "https://doi.org/10.1016/j.jcat.2008.03.016" @default.
• W1970740618 hasPublicationYear "2008" @default.
• W1970740618 type Work @default.
• W1970740618 sameAs 1970740618 @default.
• W1970740618 citedByCount "50" @default.
• W1970740618 countsByYear W19707406182012 @default.
• W1970740618 countsByYear W19707406182013 @default.
• W1970740618 countsByYear W19707406182014 @default.
• W1970740618 countsByYear W19707406182015 @default.
• W1970740618 countsByYear W19707406182016 @default.
• W1970740618 countsByYear W19707406182017 @default.
• W1970740618 countsByYear W19707406182018 @default.
• W1970740618 countsByYear W19707406182019 @default.
• W1970740618 countsByYear W19707406182020 @default.
• W1970740618 countsByYear W19707406182021 @default.
• W1970740618 countsByYear W19707406182023 @default.
• W1970740618 crossrefType "journal-article" @default.
• W1970740618 hasAuthorship W1970740618A5007349453 @default.
• W1970740618 hasAuthorship W1970740618A5007424456 @default.
• W1970740618 hasAuthorship W1970740618A5034626467 @default.
• W1970740618 hasAuthorship W1970740618A5056500440 @default.
• W1970740618 hasConcept C118792377 @default.
• W1970740618 hasConcept C124681953 @default.
• W1970740618 hasConcept C147789679 @default.
• W1970740618 hasConcept C150394285 @default.
• W1970740618 hasConcept C161790260 @default.
• W1970740618 hasConcept C175583648 @default.
• W1970740618 hasConcept C178790620 @default.
• W1970740618 hasConcept C179104552 @default.
• W1970740618 hasConcept C185592680 @default.
• W1970740618 hasConcept C2778077586 @default.
• W1970740618 hasConcept C2778533180 @default.
• W1970740618 hasConcept C2780091686 @default.
• W1970740618 hasConcept C540031477 @default.
• W1970740618 hasConcept C65024703 @default.
• W1970740618 hasConceptScore W1970740618C118792377 @default.
• W1970740618 hasConceptScore W1970740618C124681953 @default.
• W1970740618 hasConceptScore W1970740618C147789679 @default.
• W1970740618 hasConceptScore W1970740618C150394285 @default.
• W1970740618 hasConceptScore W1970740618C161790260 @default.
• W1970740618 hasConceptScore W1970740618C175583648 @default.
• W1970740618 hasConceptScore W1970740618C178790620 @default.

• next