Matches in SemOpenAlex for { <https://semopenalex.org/work/W1970770823> ?p ?o ?g. }
Showing items 1 to 72 of
72
with 100 items per page.
- W1970770823 endingPage "1776" @default.
- W1970770823 startingPage "1771" @default.
- W1970770823 abstract "Skeletal isomerization of 1-pentene to 2-methyl-1-butene (2M1B) and 2-methyl-2-butene (2M2B) provides the precursors for etherification with methanol to produce tertiary amyl methyl ether (TAME), an oxygenate fuel additive for octane improvement. Although the technology has been proven commercially, the use of a Fischer−Tropsch (FT)-derived pentene feed has not been examined previously. In this work, the effect of oxygenates present in an FT-derived pentene feed on conversion, selectivity, and the deactivation of a commercial catalyst is described. The results are compared with those obtained with a model feed containing no oxygenates and also with an FT feed from which the oxygenates have been removed. The presence of oxygenates in the feed required a start of run temperature above 320 °C to prevent competitive adsorption with the olefins, but these higher temperatures led to rapid catalyst deactivation. Oxygenates could successfully be removed from the FT feed by n-methylpyrolidone wash. This resulted in a longer catalyst cycle length (10−12 months) than in the presence of oxygenates (1−2 months)." @default.
- W1970770823 created "2016-06-24" @default.
- W1970770823 creator A5033652171 @default.
- W1970770823 date "2006-08-26" @default.
- W1970770823 modified "2023-09-27" @default.
- W1970770823 title "Skeletal Isomerization of Fischer−Tropsch-Derived Pentenes: The Effect of Oxygenates" @default.
- W1970770823 cites W1967393182 @default.
- W1970770823 cites W1978035987 @default.
- W1970770823 cites W1983441667 @default.
- W1970770823 cites W2002973074 @default.
- W1970770823 cites W2021377912 @default.
- W1970770823 cites W2042444832 @default.
- W1970770823 cites W2065620043 @default.
- W1970770823 cites W2067427827 @default.
- W1970770823 cites W2070067227 @default.
- W1970770823 cites W2077946497 @default.
- W1970770823 cites W2085577277 @default.
- W1970770823 cites W2085948217 @default.
- W1970770823 cites W2094949045 @default.
- W1970770823 cites W2144309558 @default.
- W1970770823 cites W2915397290 @default.
- W1970770823 cites W31819663 @default.
- W1970770823 doi "https://doi.org/10.1021/ef0601162" @default.
- W1970770823 hasPublicationYear "2006" @default.
- W1970770823 type Work @default.
- W1970770823 sameAs 1970770823 @default.
- W1970770823 citedByCount "17" @default.
- W1970770823 countsByYear W19707708232012 @default.
- W1970770823 countsByYear W19707708232016 @default.
- W1970770823 crossrefType "journal-article" @default.
- W1970770823 hasAuthorship W1970770823A5033652171 @default.
- W1970770823 hasConcept C108285982 @default.
- W1970770823 hasConcept C118792377 @default.
- W1970770823 hasConcept C126661725 @default.
- W1970770823 hasConcept C161790260 @default.
- W1970770823 hasConcept C178790620 @default.
- W1970770823 hasConcept C185592680 @default.
- W1970770823 hasConcept C2776164856 @default.
- W1970770823 hasConcept C2778597550 @default.
- W1970770823 hasConcept C2779607525 @default.
- W1970770823 hasConcept C62192006 @default.
- W1970770823 hasConceptScore W1970770823C108285982 @default.
- W1970770823 hasConceptScore W1970770823C118792377 @default.
- W1970770823 hasConceptScore W1970770823C126661725 @default.
- W1970770823 hasConceptScore W1970770823C161790260 @default.
- W1970770823 hasConceptScore W1970770823C178790620 @default.
- W1970770823 hasConceptScore W1970770823C185592680 @default.
- W1970770823 hasConceptScore W1970770823C2776164856 @default.
- W1970770823 hasConceptScore W1970770823C2778597550 @default.
- W1970770823 hasConceptScore W1970770823C2779607525 @default.
- W1970770823 hasConceptScore W1970770823C62192006 @default.
- W1970770823 hasIssue "5" @default.
- W1970770823 hasLocation W19707708231 @default.
- W1970770823 hasOpenAccess W1970770823 @default.
- W1970770823 hasPrimaryLocation W19707708231 @default.
- W1970770823 hasRelatedWork W128734913 @default.
- W1970770823 hasRelatedWork W1976105594 @default.
- W1970770823 hasRelatedWork W1982865822 @default.
- W1970770823 hasRelatedWork W2068100345 @default.
- W1970770823 hasRelatedWork W2386553014 @default.
- W1970770823 hasRelatedWork W2810328756 @default.
- W1970770823 hasRelatedWork W3037628611 @default.
- W1970770823 hasRelatedWork W3135595102 @default.
- W1970770823 hasRelatedWork W3196854426 @default.
- W1970770823 hasRelatedWork W3199984297 @default.
- W1970770823 hasVolume "20" @default.
- W1970770823 isParatext "false" @default.
- W1970770823 isRetracted "false" @default.
- W1970770823 magId "1970770823" @default.
- W1970770823 workType "article" @default.