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• W1970775243 abstract "CuGaSe 2 single-crystal films are grown on the As-stabilized (2×4) surface of (001) GaAs by migration-enhanced epitaxy (MEE), where Cu+Ga and Se are alternately deposited. The growth process is monitored by refraction high-energy electron diffraction (RHEED) in the [110] azimuth. Under the Cu-enriched growth condition, a deformed 4-fold pattern is observed in both Cu+Ga and Se deposition periods. The deformed 4-fold pattern is found to be related to the segregation of Cu 2 Se on the CuGaSe 2 surface as confirmed by the results of X-ray diffraction (XRD) measurement. By reducing the beam equivalent pressure of Cu (Cu-BEP), clear 4-fold patterns appear in both Cu+Ga and Se deposition periods instead of deformed 4-fold patterns. Further reduction of Cu-BEP results in clear 4- and 2-fold patterns for Cu+Ga and Se deposition periods. Under these growth conditions, Cu 2 Se-segregation-free CGS growth is achieved. Thus, the CuGaSe 2 single-crystal layers without Cu 2 Se-segregation are successfully grown on GaAs(001) substrates by optimizing the Cu-BEP." @default.
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• W1970775243 date "2011-12-01" @default.
• W1970775243 modified "2023-09-27" @default.
• W1970775243 title "Growth of CuGaSe₂ Layers on Closely Lattice-Matched GaAs Substrates by Migration-Enhanced Epitaxy" @default.
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• W1970775243 doi "https://doi.org/10.1143/jjap.50.125502" @default.
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