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- W1970787375 abstract "Abstract A complex of 5,5′-dibromo-2,2′-biphenol with 7-methyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene (MTBD) hydrochloride has been studied using X-ray diffraction, FT-IR, and 1H NMR spectroscopy. The compound crystallises in the space group P21/c with a=9.738(2), b=12.100(2), c=18.347(4) A , β=92.62(3)° (at 100 K), and Z=4. In the crystal structure, the MTBDH+ cation, a chloride anion, and one molecule of 5,5′-dibromo-2,2′-biphenol are present. In the solid state the Cl− anion is an acceptor in N+–H⋯Cl−, O–H⋯Cl− and C–H⋯Cl− intermolecular hydrogen bonds. In chloroform the structure of the complex is comparable with that in the solid, whereas in acetonitryle the complex assumes a new structure owing to the almost complete dissociation of the protonated MTBD molecule. The 5,5′-dibromo-2,2′-biphenol molecule is hydrogen-bonded with the chloride anion. Within this complex the OH⋯OH hydrogen bond shows very large proton polarisability indicated by the continuous absorption in the FTIR spectrum." @default.
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- W1970787375 date "2001-09-01" @default.
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- W1970787375 title "Crystal and molecular structure of a complex formed between the hydrochloride of 7-methyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene and 5,5′-dibromo-2,2′-biphenol" @default.
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- W1970787375 doi "https://doi.org/10.1016/s0022-2860(01)00488-4" @default.
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