Matches in SemOpenAlex for { <https://semopenalex.org/work/W1970789810> ?p ?o ?g. }
Showing items 1 to 87 of
87
with 100 items per page.
- W1970789810 endingPage "2628" @default.
- W1970789810 startingPage "2617" @default.
- W1970789810 abstract "Abstract Conductometric titration curves of MO(OR)4, and MO2(OR)2 (M = Mo, W; R = Et, iPr, C2H4OMe) by sodium (or lithium) alkoxides have ultimately proved the existence of the (1:1) bimetallic complexes in alcohol solutions. Upon evaporation of the solvents from the solutions, decomposition of the complexes occurs, accompanied by the elimination of ether, resulting in the precipitation of Na2MoO4; the molybdenum derivatives decompose more readily than the corresponding tungsten species. Under special conditions the crystals of [NaWO(OEt)5(EtOH)2]2 (I) and [NaMo2O4(OR)5(ROH)]2 [R =iPr (VI), Et (VIII)] complexes have been isolated. [NaMoO2(OC2H4OMe)3]2 (XI) proved to be the only stable complex. Solubility isotherms in the systems WO(OEt)4-M(OEt)n-EtOH and MoO2(OC2H4OMe)2- M(OC2H4OMe)2-M(OC2H4OMe)n-MeOC2H4OH (M = Na, Bi) were measured which allowed us to establish the regions of stability of the complexes. The nature of the MO bonding in the synthesized bimetallic complexes is discussed on the basis of their crystal structures and IR spectra." @default.
- W1970789810 created "2016-06-24" @default.
- W1970789810 creator A5036513853 @default.
- W1970789810 creator A5043928569 @default.
- W1970789810 creator A5065412531 @default.
- W1970789810 date "1991-01-01" @default.
- W1970789810 modified "2023-09-26" @default.
- W1970789810 title "Molybdenum and tungsten (VI) bimetallic alkoxides. Decomposition accompanied by dialkylether elimination" @default.
- W1970789810 cites W1971085989 @default.
- W1970789810 cites W1973558775 @default.
- W1970789810 cites W1974340790 @default.
- W1970789810 cites W1974994287 @default.
- W1970789810 cites W1984249175 @default.
- W1970789810 cites W1986096114 @default.
- W1970789810 cites W2017023358 @default.
- W1970789810 cites W2018429624 @default.
- W1970789810 cites W2022591490 @default.
- W1970789810 cites W2027029146 @default.
- W1970789810 cites W2027592353 @default.
- W1970789810 cites W2047246316 @default.
- W1970789810 cites W2052835015 @default.
- W1970789810 cites W2063998994 @default.
- W1970789810 cites W2106089469 @default.
- W1970789810 cites W2127264952 @default.
- W1970789810 cites W2132663412 @default.
- W1970789810 cites W2149446731 @default.
- W1970789810 cites W2166341744 @default.
- W1970789810 cites W2951476374 @default.
- W1970789810 cites W2952291703 @default.
- W1970789810 cites W2952876921 @default.
- W1970789810 cites W306699662 @default.
- W1970789810 cites W3184072210 @default.
- W1970789810 doi "https://doi.org/10.1016/s0277-5387(00)81337-6" @default.
- W1970789810 hasPublicationYear "1991" @default.
- W1970789810 type Work @default.
- W1970789810 sameAs 1970789810 @default.
- W1970789810 citedByCount "80" @default.
- W1970789810 countsByYear W19707898102012 @default.
- W1970789810 countsByYear W19707898102013 @default.
- W1970789810 countsByYear W19707898102014 @default.
- W1970789810 countsByYear W19707898102015 @default.
- W1970789810 countsByYear W19707898102016 @default.
- W1970789810 countsByYear W19707898102017 @default.
- W1970789810 countsByYear W19707898102018 @default.
- W1970789810 countsByYear W19707898102022 @default.
- W1970789810 countsByYear W19707898102023 @default.
- W1970789810 crossrefType "journal-article" @default.
- W1970789810 hasAuthorship W1970789810A5036513853 @default.
- W1970789810 hasAuthorship W1970789810A5043928569 @default.
- W1970789810 hasAuthorship W1970789810A5065412531 @default.
- W1970789810 hasConcept C124681953 @default.
- W1970789810 hasConcept C161790260 @default.
- W1970789810 hasConcept C178790620 @default.
- W1970789810 hasConcept C179104552 @default.
- W1970789810 hasConcept C185592680 @default.
- W1970789810 hasConcept C43411465 @default.
- W1970789810 hasConcept C542268612 @default.
- W1970789810 hasConcept C549387045 @default.
- W1970789810 hasConceptScore W1970789810C124681953 @default.
- W1970789810 hasConceptScore W1970789810C161790260 @default.
- W1970789810 hasConceptScore W1970789810C178790620 @default.
- W1970789810 hasConceptScore W1970789810C179104552 @default.
- W1970789810 hasConceptScore W1970789810C185592680 @default.
- W1970789810 hasConceptScore W1970789810C43411465 @default.
- W1970789810 hasConceptScore W1970789810C542268612 @default.
- W1970789810 hasConceptScore W1970789810C549387045 @default.
- W1970789810 hasIssue "22" @default.
- W1970789810 hasLocation W19707898101 @default.
- W1970789810 hasOpenAccess W1970789810 @default.
- W1970789810 hasPrimaryLocation W19707898101 @default.
- W1970789810 hasRelatedWork W1970789810 @default.
- W1970789810 hasRelatedWork W1978223435 @default.
- W1970789810 hasRelatedWork W2014092843 @default.
- W1970789810 hasRelatedWork W2041739411 @default.
- W1970789810 hasRelatedWork W2045443807 @default.
- W1970789810 hasRelatedWork W2062225457 @default.
- W1970789810 hasRelatedWork W2075417152 @default.
- W1970789810 hasRelatedWork W2089371673 @default.
- W1970789810 hasRelatedWork W2366692166 @default.
- W1970789810 hasRelatedWork W2952757745 @default.
- W1970789810 hasVolume "10" @default.
- W1970789810 isParatext "false" @default.
- W1970789810 isRetracted "false" @default.
- W1970789810 magId "1970789810" @default.
- W1970789810 workType "article" @default.