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• W1970818224 startingPage "2139" @default.
• W1970818224 abstract "Cd(II) halide complexes [Cd 2 X 4 (tpa) 2 ] ( 1 : X = Cl, 2 : X = Br, 3 : X = I; tpa = tris(2-pyridyl)amine) have been synthesized. X-Ray diffraction analyses of 2 and 3 reveal their asymmetrical dinuclear structures: one Cd(II) atom is octahedrally coordinated to four N atoms of two tpa ligands and two bridging halides; the other Cd(II) is tetrahedrally coordinated to two terminal (X (t) ) and two bridging (X (b) ) halides. By multiple intra- and intermolecular π-π interactions between the tpa pyridine rings, the ligands of 2 and 3 are linked to form a 2D network and 1D linear structures, respectively. In the Raman and far-infrared spectra, the absorption bands due to Cd-X (b) stretching modes lie at lower wavenumbers compared to the Cd-X (t) stretches. It can be inferred from the spectroscopic data that 1 has a dinuclear structure similar to those of 2 and 3 ." @default.
• W1970818224 created "2016-06-24" @default.
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• W1970818224 date "2003-01-01" @default.
• W1970818224 modified "2023-10-09" @default.
• W1970818224 title "Structure and Spectroscopic Studies of Cd(II) Complexes of Tris(2-pyridyl)amine: 1D and 2D Supramolecular Assemblies" @default.
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• W1970818224 doi "https://doi.org/10.1135/cccc20032139" @default.
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