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- W1970898050 abstract "The synthesis of aromatic copolyamidethioethers by reaction of dichlorobenzanilides with Na2S has been studied. The reactivity of chlorine atoms is strongly dependent on the nature of the substituent in para position. It is related to the 13C NMR shifts of the relative carbons-the more deshielded, the more reactive-and hence to charge densities, agreing with aromatic nucleophilic substitution mechanisms. The results are discussed in relation to the various mechanisms which have been put forward for the reaction of Na2S with 1, 4-dichlorobenzene (PPS synthesis)." @default.
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- W1970898050 date "1991-07-01" @default.
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- W1970898050 title "Reactivity of aryl chlorides with sodium sulfide in the synthesis of aromatic polyamidethioethers" @default.
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- W1970898050 doi "https://doi.org/10.1002/masy.19910470132" @default.
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