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- W1970909360 abstract "Abstract Group theoretical techniques are employed to derive the form of the most general phenomenological rotational Hamiltonian associated with a given molecular vibrational state or set of states. The expansion is given in terms of the symmetrized products of angular momentum matrices. A perturbation expansion for the rotational states is developed based on tetrahedral distortions of a spherically symmetric distribution of mass. This jellium approximation significantly reduces the number of parameters in the rotational Hamiltonian. The specific application to methane is indicated." @default.
- W1970909360 created "2016-06-24" @default.
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- W1970909360 date "1981-06-01" @default.
- W1970909360 modified "2023-09-27" @default.
- W1970909360 title "Phenomenological molecular rotational Hamiltonians in cubic symmetry" @default.
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- W1970909360 doi "https://doi.org/10.1016/0022-2852(81)90423-9" @default.
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