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• W1970970918 startingPage "L992" @default.
• W1970970918 abstract "The mechanism of azimuthal reorientation of nematic liquid crystals induced by linearly polarized light irradiation of thin films of polymers with cinnamate side chains has been discussed. It has been concluded that the photoalignment is induced not by the polarized photodimerization, but by polarized photoisomerization, based on the following results. First, spectral analysis of olefinic chromophores upon UV irradiation has shown that a predominant photochemistry in films is the E/Z photoisomerization which results in the dichroism of the chromophores. Second, the alignment direction can be altered by subsequent irradiation with polarized light with a different electric vector. Photodimerization plays a role in enhancing the thermal stability of photoalignment." @default.
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• W1970970918 date "1996-08-01" @default.
• W1970970918 modified "2023-09-27" @default.
• W1970970918 title "Role of E/Z Photoisomerization of Cinnamate Side Chains Attached to Polymer Backbones in the Alignment Photoregulation of Nematic Liquid Crystals^*1" @default.
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• W1970970918 doi "https://doi.org/10.1143/jjap.35.l992" @default.
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