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- W1971016411 abstract "The synthesis of nano-sized SiC through ball milling (BM) of elemental Si and graphite mixed powders at room temperature has been reported, and detailed reaction process has been characterized by high-resolution electron microscopy (HREM). High-resolution electron microscopy (HREM) observations presented herein suggest that amorphous graphite (a-graphite), amorphous silicon (a-Si) and nano-sized crystalline Si (c-Si) with many defects are produced during BM, which is prerequisite to the reaction. In some areas, SiC is synthesized through a diffusion of C atoms into the a-Si/and c-Si. In the former, a-Si(C) forms, and then mechanically-driven crystallization of the a-Si(C) occurs to form SiC. In the latter, C atoms directly replace Si atoms to form SiC with an orientation relationship of (111)SiC//(111)Si. In other areas, localized self-sustained reaction occurs to form slightly larger SiC grains." @default.
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- W1971016411 date "2001-02-01" @default.
- W1971016411 modified "2023-09-27" @default.
- W1971016411 title "HREM observations of the synthesized process of nano-sized SiC by ball milling of Si and C mixed powders" @default.
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- W1971016411 doi "https://doi.org/10.1016/s0921-5093(00)01293-4" @default.
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