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- W1971026400 abstract "5-Imino-1,2,4-thiadiazolidin-3-ones 1 react with compounds containing electron-rich double bonds such as enamines and ester enolates to afford the 2-iminothiazolidines 3, 4, and 10 in cycloaddition−elimination reactions. The less reactive 5-imino-1,2,4-dithiazolidin-3-ones 2 only give the 2-iminothiazolidines 3 or 4 with enamines; with ester enolates the 5-alkylidene-1,2,4-dithiazolidines 12 are formed. The reaction products with enamines undergo hydrolysis and elimination to form the corresponding hydroxy compounds 5, 6 or the unsaturated compounds 7, 8, depending on the size of the fused ring." @default.
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- W1971026400 date "1998-03-01" @default.
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- W1971026400 title "Cycloaddition−Elimination Reactions of 5-Imino-1,2,4-thiadiazolidin-3-ones and 5-Imino-1,2,4-dithiazolidin-3-ones with Electron-Rich Double Bonds" @default.
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- W1971026400 doi "https://doi.org/10.1002/(sici)1099-0690(199803)1998:3<515::aid-ejoc515>3.0.co;2-6" @default.
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