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- W1971031544 abstract "The Gibbs free energy differences between amorphous alloys and solid solutions, ΔG a–ss, and the Gibbs free-energy of formation of amorphous alloy, ΔG a–c, in Gd–Ni(Co)–Al ternary alloy systems are calculated with a semi-empirical model based on the Miedema's theory to find a correlation between them and experimentally obtained data on glass-forming ability (GFA) and thermal stability. It is found that Gd–Ni(Co)–Al bulk metallic glasses (BMGs) form well in the BMG forming region, in which corresponding alloys have high negative values of ΔG a–ss, with a value of configurational entropy normalized by the gas constant, S config/R, lying in the range from 0.8 to 1. On the other hand, there is a strong linear dependence of the thermal stability on ΔG a–c, which can thus be used as an effective parameter to predict the thermal stability of a given glass in a narrow composition region." @default.
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- W1971031544 date "2009-01-01" @default.
- W1971031544 modified "2023-10-18" @default.
- W1971031544 title "Thermodynamic analysis of Gd–Ni(Co)–Al bulk metallic glasses" @default.
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- W1971031544 doi "https://doi.org/10.1080/09500830802613139" @default.
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