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- W1971032007 abstract "Palladium-catalyzed coupling reactions of 6,6‘-dihydroxyboron-2,2‘-dimethoxy-1,1‘-binaphthyl 5g and chloroarenetricarbonylchromium complexes 6a−c afforded complexes 7a−c with the binaphthyl residue directly linked to the (η6-arene)tricarbonylchromium entity. Coupling reactions of 2,2‘-dimethoxy, 3,3‘-diodo, and 6,6‘-diodo-1,1‘-binaphthyl 3h and 5h with ethynylarenetricarbonylchromium derivatives 6d−f and ethynylferrocene 9 yielded binaphthyl compounds linked to arenetricarbonylchromium and ferrocenyl derivatives 8a−c, 11a−c, 10, and 12 through a triple bond. Condensation of 2,2‘-dimethylmethoxy, 3-formyl, 1,1‘-binaphthyl 2a with (η6-phenyl)methyltriphenylphosphonium tricarbonylchromium 13 and ferrocenylmethyltriphenylphosphonium 18 gave binaphthyl compounds linked to arenetricarbonylchromium and ferrocenyl derivatives 14 and 19, respectively, through a double bond. X-ray analyses of the dinuclear chromium complex 8a and of the mononuclear chromium complex 17-Z are described." @default.
- W1971032007 created "2016-06-24" @default.
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- W1971032007 date "2007-10-30" @default.
- W1971032007 modified "2023-10-12" @default.
- W1971032007 title "(η<sup>6</sup>-Arene)tricarbonylchromium and Ferrocene Complexes Linked to Binaphthyl Derivatives" @default.
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- W1971032007 doi "https://doi.org/10.1021/om700586z" @default.
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