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- W1971035596 abstract "The spectrum of CH3D has been studied between 1040 and 1280 cm−1 with a Czerny-type spectrometer having a resolving power of 0.1 cm−1. In the perpendicular ν6 band, a strong l-type doubling is taking place. In addition it is necessary to introduce a resonance of the type l(2, 2). Further improvement of the calculation is obtained by using an energy expansion including the third order correction E3 = kl[η6JJ(J + 1) + η6Kk2]. We have determined the values of η6J and η6K which are surprisingly large compared to the D constants. A Coriolis interaction between ν6 and the parallel ν3 band (centered near 1307 cm−1) has been investigated. In spite of the small value of the coupling coefficient ζ3,6x, the existence of this resonance is unquestionable. Moreover, aK-type doubling in the PP3 and PQ3 branches was analysed and the corresponding γ coefficient was evaluated." @default.
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- W1971035596 date "1972-08-01" @default.
- W1971035596 modified "2023-10-01" @default.
- W1971035596 title "Resonances and doublings in the infrared spectrum of CH3D at 9" @default.
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- W1971035596 doi "https://doi.org/10.1016/0022-2852(72)90015-x" @default.
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